The forward sprained his right ankle in a collision with Serbia’s Nikola Milenkovic in Brazil’s 2-0 win on Thursday.
Neymar played on for 11 minutes before coming off, right, when it became clear he could not continue.
He was initially ruled out of just Monday’s meeting with Switzerland.
But it has been confirmed the Paris Saint-Germain star will also miss Brazil’s final Group G game, against Cameroon next Friday.
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