The striker drew level with Jimmy Greaves on 266 Spurs goals when he netted a superb strike in the 1-0 Premier League win at Fulham on Monday.
Greaves' tally had stood untouched since 1970, but the England captain is now on the verge of sole possession of the record.
Manager Antonio Conte could rest his stars against second-tier Preston as his fifth-placed team are in the midst of a fight to climb back into the EPL's top four.
But, mindful of Tottenham's surprise defeat at Middlesbrough in the FA Cup fifth round last season, Kane is keen to play.
"The FA Cup is important for us. It was disappointing to lose to Middlesbrough. We will see what the manager says but I will be ready," said Kane, who is still looking to win the first major trophy of his career.
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